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![]() via Ellis Island by ship in the late 19th and early 20th centuries, and is a symbol of the U.S. The Statue of Liberty greeted millions of immigrants as they came to the U.S. New York City was the capital of the United States from 1785 until 1790, and has been the largest U.S. The city was temporarily regained by the Dutch in July 1673 and was renamed New Orange the city has been named New York since November 1674. The city came under British control in 1664 and was renamed New York after King Charles II granted the lands to his brother, the Duke of York. The settlement was named New Amsterdam ( Dutch: Nieuw Amsterdam) in 1626 and was chartered as a city in 1653. New York City traces its origins to Fort Amsterdam and a trading post founded on the southern tip of Manhattan Island by Dutch colonists in approximately 1624. The city is home to more than 3.2 million residents born outside the U.S., the largest foreign-born population of any city in the world as of 2016. As many as 800 languages are spoken in New York, making it the most linguistically diverse city in the world. ![]() The city and its metropolitan area are the premier gateway for legal immigration to the United States. With over 20.1 million people in its metropolitan statistical area and 23.5 million in its combined statistical area as of 2020, New York City is one of the world's most populous megacities. New York is the geographical and demographic center of both the Northeast megalopolis and the New York metropolitan area, the largest metropolitan area in the U.S. NYC has more than double the population of Los Angeles, the nation's second-most populous city. With a census-estimated population of 8,335,897 distributed over 300.46 square miles (778.2 km 2) in 2022, the city is the most densely populated major city in the United States. It is sometimes described as the world's most important city and the capital of the world. Home to the headquarters of the United Nations, New York is an important center for international diplomacy. It is a global city and a cultural, financial, high-tech, entertainment, and media center with a significant influence on commerce, health care, scientific output, life sciences, research, technology, education, politics, tourism, dining, art, fashion, and sports. The city comprises five boroughs, each of which is coextensive with a respective county. New York, often called New York City or simply NYC, is the most populous city in the United States located at the southern tip of New York State on one of the world's largest natural harbors. ![]() It’s not clear whether Salesforce will take up the reins on this case once the Slack acquisition has cleared, but it’s hard to imagine Salesforce will want to pursue it any further. Slack argues that Microsoft is using its market dominance with Office to force millions of people to install Teams, with no way of removing it or even knowing how much it costs. The crux of the complaint is that while Slack is broadly available as a standalone service and application with various pricing tiers, Microsoft Teams comes as part of an Office 365 subscription, (though a free version of Teams is available too). “Slack has some considerable differentiators still in the market, but the effects of the pandemic and the shift to remote work have made the competition with Microsoft even tougher, given Microsoft’s strength in video meetings, which we have all become so dependent on,” CCS Insight analyst Angela Ashenden said.Ī few months back, Slack filed an antitrust complaint against Microsoft in the EU for bundling Teams with Office, asking the European Commission (EC) to take “swift action to ensure Microsoft cannot continue to illegally leverage its power from one market to another by bundling or tying products.” He has also noted that “Microsoft benefits from the narrative” that Teams is a direct competitor to Slack.Īmplified by the COVID-19 crisis, which has driven companies to remote collaboration tools - particularly video - Teams has been on the front foot throughout 2020. Indeed, Butterfield has long argued that Teams isn’t a true Slack competitor as Teams is used primarily for voice and video calls, similar to Zoom. But relations have soured, with Butterfield often calling Microsoft out over the way it bundles Teams with its broader Office suite, alleging that Microsoft misleads the public with its Teams’ daily active users (DAUs) data to make it seem more popular than Slack. Microsoft launched its Teams platform back in 2016 and has enjoyed a healthy rivalry with Slack, which even took out a full-page ad in the New York Times giving Microsoft tips on how to succeed in the team communication sphere. Slack’s slackingĭespite Slack’s popularity in the workforce, it has been at a major disadvantage compared to the deep-pocketed and expansive Microsoft, which has a huge ecosystem of products it can attach Teams to. ![]() Slack also recently launched Slack Connect, enabling up to 20 organizations to communicate in a single Slack channel, which could help Salesforce teams communicate with sales prospects and other external partners. ![]() According to Salesforce, Slack will become the “new interface for Salesforce Customer 360” and will be “deeply integrated into every Salesforce cloud,” becoming the core conduit through which people “communicate, collaborate, and take action on customer information.” ![]() With the Slack acquisition, Salesforce now has a direct path to social collaboration across the enterprise, allowing it to create deeper integrations for its array of products. In fact, Salesforce already offers integrations that allow users to share messages between Chatter and Slack, a possible indication that despite its clear market strength in certain areas, it still lags in others. Salesforce already has an enterprise-focused social platform called Chatter, but the largely sales-focused tool hasn’t really taken off. Salesforce and Slack have a long-established relationship, thanks to product integrations over several years aimed at making it easier for enterprises to share data between the two platforms. The transaction is expected to close in Q2 of Salesforce’s fiscal year 2022, which falls in the second half of 2021, after which Slack will become an operating unit inside Salesforce, led by current Slack CEO and cofounder Stewart Butterfield. This has a high melting point (800 ✬) and dissolves in water to to give a conducting solution. When sodium is burned in a chlorine atmosphere, it produces the compound sodium chloride. Why do the atoms of many elements interact with each other and with other elements to give stable molecules? In addressing this question it is instructive to begin with a very simple model for the attraction or bonding of atoms to each other, and then progress to more sophisticated explanations. Some dramatic examples of this reactivity are shown in the following equations. In contrast, other gaseous elements exist as diatomic molecules (H 2, N 2, O 2, F 2 & Cl 2), and all but nitrogen are quite reactive. Its location in the periodic table should not suggest a kinship to the chemistry of the alkali metals, and its role in the structure and properties of organic compounds is unlike that of any other element.Īs noted earlier, the inert gas elements of group 8 exist as monoatomic gases, and do not in general react with other elements. It should be noted that hydrogen is unique. The elements in groups 2 through 7 all exhibit characteristic reactivities and bonding patterns that can in large part be rationalized by their electron configurations. As a consequence of this electron loss, these elements are commonly encountered as cations (positively charged atoms). These atoms have only one electron in the valence shell, and on losing this electron arrive at the lower shell valence octet. (colored violet above) are also exceptionally reactive, but for the opposite reason. In their chemical reactions halogen atoms achieve a valence shell octet by capturing or borrowing the eighth electron from another atom or molecule. The halogens (F, Cl, Br etc.) are one electron short of a valence shell octet, and are among the most reactive of the elements (they are colored red in this periodic table). ![]() In the periodic table above these elements are colored beige. This group of inert (or noble) gases also includes krypton (Kr: 4s 2, 4p 6), xenon (Xe: 5s 2, 5p 6) and radon (Rn: 6s 2, 6p 6). The other members of group 8 have a characteristic valence shell electron octet (ns 2 + np x 2 + np y 2 + np z 2). Helium is unique since its valence shell consists of a single s-orbital. For example, helium, neon and argon are exceptionally stable and unreactive monoatomic gases. The chemical properties of the elements reflect their electron configurations. The highest occupied electron shell is called the valence shell, and the electrons occupying this shell are called valence electrons. In the third period of the table, the atoms all have a neon-like core of 10 electrons, and shell #3 is occupied progressively with eight electrons, starting with the 3s-orbital. As we progress from lithium (atomic number=3) to neon (atomic number=10) across the second row or period of the table, all these atoms start with a filled 1s-orbital, and the 2s-orbital is occupied with an electron pair before the 2p-orbitals are filled. Shell #2 has four higher energy orbitals, the 2s-orbital being lower in energy than the three 2p-orbitals. According to the Aufbau principle, the electrons of an atom occupy quantum levels or orbitals starting from the lowest energy level, and proceeding to the highest, with each orbital holding a maximum of two paired electrons (opposite spins).Įlectron shell #1 has the lowest energy and its s-orbital is the first to be filled. The truncated periodic table shown above provides the orbital electronic structure for the first eighteen elements (hydrogen through argon). ![]() Consequently, our understanding of organic chemistry must have, as a foundation, an appreciation of the electronic structure and properties of these elements. Other interactive periodic tables provide comprehensive data for each element, including nuclide properties, environmental and health factors, presentation in different languages and much more.įor comic relief you may wish to examine a periodic table linked to element references in comic books.įour elements, hydrogen, carbon, oxygen and nitrogen, are the major components of most organic compounds. There are, of course, over eighty other elements.Ī complete periodic table, having very useful interactive links has been created by Mark Winter. The periodic table shown here is severely truncated. This module introduces some basic facts and principles that are needed for a discussion of organic molecules.Įlectron Configurations in the Periodic Table 1A The study of organic chemistry must at some point extend to the molecular level, for the physical and chemical properties of a substance are ultimately explained in terms of the structure and bonding of molecules. ![]() Electron Configurations & The Periodic Table Trademarks: Dell Technologies, Dell and other trademarks are trademarks of Dell Inc. PayPal: Subscription products are not eligible for Pay in 4 Dell reserves the right to cancel orders arising from pricing or other errors. Free shipping offer valid only in Continental U.S. Dell may impose a purchase quantity limit (for example, 5 units per order). Offer details: Offers subject to change, not combinable with all other offers, while supplies last. Third-party retailer data may not be based on actual sales. This Logitech G Pro X wired gaming headset has onboard memory that accommodates equalizer profiles for customized sound reproduction.Įstimated value is Dell’s estimate of product value based on industry data, including the prices at which third-party retailers have offered or valued the same or comparable products, in its most recent survey of major online and/or off-line retailers. The memory foam earpads are made of noise-isolating leatherette and breathable velour for comfort, and the external USB sound card processes digital signals to deliver realistic game sounds. The 2-inch drivers have a hybrid mesh construction for durability and deliver crisp, powerful sound for an all-around gaming experience.Ī compact, lightweight profile and a protective travel bag support safe carrying, and the 3.5mm detachable cable ensures compatibility with a variety of devices. A detachable 6mm Blue VOICE cardioid microphone helps you plan battlefield strategies, while the durable steel and aluminum construction stands up to daily use, letting you complete in-game missions seamlessly. Lead your team to victory with this Logitech G Pro X wired gaming headset. The 7.1 channel surround system delivers crisp, powerful sound, keeping you aware of your immediate environment to prevent surprise attacks on your team. ![]() Intensify your gaming experience with this Logitech G Pro X wired gaming headset.
It begins with a brief explanation of how you can import images into the Catalog, then takes users through the basic layout of the Edit workspace and how they can quickly apply one of Luminar Neo’s many Presets. This excellent tutorial for beginners delivers an excellent primer on how to use Luminar Neo for newcomers to the software, whether you’re an experienced photographer accustomed to other post-processing software or a complete newbie who needs walking through the various tools. ![]() Complete Luminar Neo tutorial for beginners With that said, let’s start at the beginning with a great Luminar Neo tutorial for beginners to help get you oriented with the settings and tools you need to know. ![]() There are also advanced tutorials that I’ll dive into, which are designed for specific tasks, including comprehensive tutorials for landscape and portrait editing that explore a broad selection of tools you can apply to this shooting style. While Luminar Neo is popular among both amateur photographers and working professionals, these tutorials can be of great help to anyone who’s new to the software and wants to quickly find their way around it. ![]() Luminar Neo has many exceptional tools you can use to edit your photographs, in addition to a broad selection of presets, and the best Luminar Neo tutorials help you to discover and use these tools to the best of your abilities. Best Luminar Neo Tutorials (From Beginner’s Guides to Advanced Processes) Call Show Number Email Send Email Website Visit Website. Your 1098 interest statement for 2023 will be mailed and available online by January 31st. Because of this, the company is grounded in its core values, and focused on high ethics and creating a 5-star experience for our customers, our partners, and our employees. 700 Rockmead Drive, Building 2, Ste 102, kingwood, TX 77339. Sente not only survived, but thrived during this chaotic time because we started fresh and were able to predict what the mortgage landscape would look like in the coming years. S ente’s owners believed they could build a mortgage company that was purpose-driven, relationship-based, and ethically grounded. This concept eventually formed the foundation for our company’s purpose, “We Create Financial Possibility.” 1521 Green Oak Pl 197, Humble, TX 77339, USA Houston, TX 77339. We adopted the term Sente as the name for the company as a metaphor for helping people “win at their financial game” or, better said, create a strong financial situation. Sente Mortgage made everything clear and easy for me Show more. The name Sente comes from a term used in the ancient strategy game Go and represents the winning position on the Go board. In fact, it is one of the reasons the company is named Sente. 77339, Everytime i burp it tastes like eggs, Framed hand painted wall art. Since its inception, Sente Mortgage had a vision to be a different kind of mortgage company - not just a place for mortgages, but a place to create financial possibility. mortgage, Best dry dog food for golden retrievers, Korean embassy travel to. 4520 Burnet Rd, Austin, Texas, 78756, United States. While many companies were closing their doors, we launched with a different name and a different model. Sente Mortgage is part of the Banking industry, and located in Texas, United States. Sente launched in 2007 during one of the most tumultuous times in the history of mortgage lending. ![]() Who knows how long this splendid weather will last, so take the time now to get your patio space in order. Whether you are ready to purchase or just looking, stop by and let your creative thoughts be your guide. There are also various planters and garden statues available to spruce up any style of yard or garden. For instance, check out these iron chairs with Texas motifs. These chairs have a slight rock to them and also look great with cushions. ![]() In addition to our new line, we are also carrying other styles of outdoor furniture and accessories. Walt, enjoying our new offerings at our Bissonnet location Telescope Casual Furniture may be more costly initially than some of its inferior competitors, but the brand’s attention to textile function and reliability will pay off ten-fold. When he laid eyes on this furniture he knew he had to try it out. Generally, it is resistant to moths, oils, chemicals, and deterioration due to sunlight exposure.Īccording to Walt Haralson, our Bissonnet store assistant manager, “This piece is living room chair comfortable!” Among his many other duties, Walt often assists in the buying process and selections for Bering’s. Quick tip: Acrylic fabric is a hypoallergenic alternative to high-maintenance textiles. 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Your Coffee Should Always Be This Extraordinary.Fresh Roasted Coffee from Cafe Bering’s.Find Elegant Home Accents For Timeless Style.Personalized Charcuterie + Cutting Boards.It also serves the hospitality/ contract furnishings industry with fast delivery and great customer service. It offers wicker, aluminum, cast aluminum and resin furniture in various collections and styles. I truly love them and if you like comfort and reliability give them a try and I recommend Luxe DECOR. Telescope Casual Furniture is a company that produces quality, outdoor patio furniture for over a century. I know from my experience these chairs can stay outside and they will never rust. I live in an apartment with no storage for the winter months or as they say in Seattle, the wet months. Patio Furniture Warehouse distributes to all areas of South Florida including Broward County, Miami-Dade County and West Palm County. They were packaged well and shipped, and the delivery person brought them to my apartment on the 4th floor. Patio furniture is located in Hallandale, Florida 33009. they were honest about how long it would take which was 12-16 weeks. Luxe DECOR was the right choice after scanning the web for what I wanted. ![]() Several years ago we purchased 2 metal rockers for the porch and the weld on one rocker recently failed. Weve had patio furniture from Telescope for years which has held up beautifully. We all knew the quality of the chairs and when I left and got an apartment with a large balcony I knew I wanted 2 of these chairs. 12 reviews of Telescope Casual Furniture 'This is one classy company. I lived about 20 miles from the Telescope factory in Granville NY. I owned 6 Telescope swivel rocker dining armchairs for over 15 years and I bought them used. 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